Phosphorus‐Substituted Thioformamides and Thioformimidates: Molecular Structure and Solid State 13C‐NMR Spectra
- 1 August 1985
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 24 (8) , 715-716
- https://doi.org/10.1002/anie.198507151
Abstract
The presence of two symmetry‐independent molecules in the unit cell‐not E/Z isomerism in the crystal‐is responsible for the existence of two N‐methyl signals in the solid‐state 13C‐NMR spectrum of the thioamide 1. Even small conformational differences in the molecule in the solid state have a considerable effect on the chemical shift. equation imageKeywords
This publication has 10 references indexed in Scilit:
- Phosphansubstituierte Chelatliganden, X. Bindungs‐ und Stereoisomerie tertiärer 1‐(Phosphino)thioformamide. Kristallstruktur von S ‐Methyl‐1‐(diphenylthiophosphoryl)‐ N ‐methylthioformimidat, Ph 2 P(S)C(NMe)SMeEuropean Journal of Inorganic Chemistry, 1985
- Phosphinsubstituierte Chelatliganden, IX [1]. NMR-Spektren und Kristallstruktur von Diphenyl(thio)phosphoryl-N,N-dimethylthioformamid / Phosphine Substituted Chelate Ligands, IX [1]. NMR Spectra and Crystal Structure of Diphenyl(thio)phosphoryl-N,N-dimethylthioformamideZeitschrift für Naturforschung B, 1984
- 14N quadrupole effects in CP-MAS 13C NMR spectra of organic compounds in the solid stateJournal of Magnetic Resonance (1969), 1982
- High-resolution NMR in solids: the CPMAS experimentAccounts of Chemical Research, 1982
- Ist die Konformation eines Moleküls im Kristall und in Lösung gleich? NMR-Befunde an Festkörper und Lösung im Vergleich zur Röntgen-StrukturbestimmungAngewandte Chemie, 1981
- Does a Molecule have the Same Conformation in the Crystalline State and in Solution? Comparison of NMR Results for the Solid State and Solution with those of the X‐ray Structural DeterminationAngewandte Chemie International Edition in English, 1981
- High resolution solid state 13C NMR spectra of carbons bonded to nitrogen in a sample spinning at the magic angleThe Journal of Chemical Physics, 1981
- Chemical shielding tensor and 13C–14N dipolar splitting in single crystals of L-alanineThe Journal of Chemical Physics, 1981
- Influence of nitrogen-14 on carbon-13 NMR spectra of solidsJournal of the American Chemical Society, 1981
- Alkali‐Phosphorverbindungen und ihr reaktives Verhalten, XXIX. [N‐Phenyl‐thiocarbamoyl]‐phosphineEuropean Journal of Inorganic Chemistry, 1964