A new family of nitrido carbonyl clusters. Synthesis and structural characterization of the anions [Rh6MN(CO)15]2–(MCo, Rh, or Ir), and evidence for metal atom migration in the cluster
- 1 January 1984
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 23,p. 1577-1578
- https://doi.org/10.1039/c39840001577
Abstract
The anions [Rh6MN(CO)15]2–(M Co,Rh, or Ir), obtained by condensation of [Rh6N(CO)15]– and [M(CO)4]–, contain a metallic array consisting of a trigonal prism capped on a square face, with the nitride inside the prismatic hole; the mixed-metal species show an unexpected migration of the entering metal from the capping position to the vertices of the prism.Keywords
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