Crystal Structure and Electrochemical Behavior of an Unusual Nitrosyl-Ru Complex Obtained by a Reaction of Ru2(Me COO)4 Cl with 2-Pyridinecarboxylic Acid
- 1 August 1999
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 28 (8) , 733-734
- https://doi.org/10.1246/cl.1999.733
Abstract
The crystal structure and the electrochemical behavior of a Ru-complex, which was obtained from a reaction of [Ru2(MeCOO)4Cl] with 2-pyridinecarboxylic acid and NO2−, were investigated: the complex consists of nitrosyl, 2-pyridinecarboxylato, and acetato ligands. The cyclic voltammogram showed no redox wave in the region of the potential window, unlike common Ru(NO)-complexes.This publication has 9 references indexed in Scilit:
- Crystal Structure of Bis-(2,2’-bipyridine)chloronitrosylruthenium(II) PerchlorateAnalytical Sciences, 1998
- Ruthenium Nitrosyl Complexes with N-Heterocyclic LigandsInorganic Chemistry, 1998
- Redox- and Thermally-Induced Nitro-Nitrito Linkage Isomerizations of Ruthenium(II) Complexes Having Nitrosyl as a Spectator LigandInorganic Chemistry, 1995
- Mechanism of reduction of bound nitrite to ammoniaInorganic Chemistry, 1986
- Interconversion of nitrite and ammonia: progress toward a model for nitrite reductaseJournal of the American Chemical Society, 1982
- Reactions of nitric oxide coordinated to transition metalsChemical Reviews, 1979
- Reversible electron transfer in ruthenium nitrosyl complexesInorganic Chemistry, 1977
- Principles of structure, bonding, and reactivity for metal nitrosyl complexesCoordination Chemistry Reviews, 1974
- Syntheses of Formato-, Acetato-, Benzoato-, and Chlorosubstituted Acetatoruthenium Complexes, and Their PropertiesBulletin of the Chemical Society of Japan, 1972