The stereochemistry of formation and cleavage of alkyl-transition-metal derivatives
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 16,p. 986-987
- https://doi.org/10.1039/c29700000986
Abstract
Formation of alkyl–metal compounds by displacement of halide ion from alkyl halides by transition-metal nucleophiles occurs with inversion of configuration; cleavage of the carbon–metal bond with bromine occurs with retention of configuration.Keywords
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