Palladium catalysed enantioselective phosphination reactions using secondary phosphine-boranes and aryl iodide
- 1 January 2005
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 18,p. 2393-2395
- https://doi.org/10.1039/b501078k
Abstract
Preliminary results dealing with the enantioselective version of the C–P cross-coupling reaction between dissymmetric secondary phosphine-borane complexes and aryl iodide derivatives are presented. To gain information on the enantiodiscriminating step, direct observation of an intermediate involved in the catalytic cycle has been achieved by 31P NMR spectroscopy.Keywords
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