Cyclopolymerization. V. The13C Spectrum and Structure of the Low Molecular Weight Product from the Reaction of N-Methyl-N,N-diallylamine with Azobisisobutyronitrile
- 1 January 1975
- journal article
- research article
- Published by Taylor & Francis in Journal of Macromolecular Science: Part A - Chemistry
- Vol. 9 (1) , 169-181
- https://doi.org/10.1080/00222337508068653
Abstract
A study of the 13C chemical shift data and of the shifts induced by Eu(dpm)3 has shown that the aminoketone formed in the reaction of N-methyl-N,N-diallylamine with cyanoisopropyl radicals is 2,6,6-trimethyl-cis-perhydroisoindolid-5-one (1a, R = O). The 13C NMR spectrum in the presence of acid reveals the existence of two protonated forms of this compound.Keywords
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