Hydrogen Storage Capacity of Catalytically Grown Carbon Nanofibers
- 14 July 2005
- journal article
- Published by American Chemical Society (ACS) in The Journal of Physical Chemistry B
- Vol. 109 (31) , 14979-14989
- https://doi.org/10.1021/jp051371a
Abstract
In 1996, R. T. K. Baker, and N. M. Rodriguez claimed to have synthesized a new type of carbon nanofiber material capable of storing large amounts of hydrogen at room temperature and pressures above 100 bar, thus making it a powerful candidate for a very efficient energy storage system in mobile applications. Consequently, many scientists all over the world tried to test and verify these findings, however, with partly inconsistent results. We present here for the first time independent hydrogen storage measurements for several types of nanofibers, both synthesized by our group following precisely the specifications given in the literature as well as original samples supplied by Rodriguez and Baker for this study. The hydrogen storage capacities at room temperature and pressures up to 140 bar were quantified independently by gravimetric and volumetric methods, respectively. No significant hydrogen storage capacity has been detected for all carbon nanofibers investigated.Keywords
This publication has 32 references indexed in Scilit:
- Studies into the Storage of Hydrogen in Carbon Nanofibers: Proposal of a Possible Reaction MechanismNano Letters, 2002
- Growth of well-crystallized segmented graphite nanofibers by catalytic chemical vapor depositionJournal of Crystal Growth, 2001
- Interpretation of Raman spectra of disordered and amorphous carbonPhysical Review B, 2000
- High H 2 Uptake by Alkali-Doped Carbon Nanotubes Under Ambient Pressure and Moderate TemperaturesScience, 1999
- Hydrogen desorption and adsorption measurements on graphite nanofibersApplied Physics Letters, 1998
- The effect of copper on the structural characteristics of carbon filaments produced from iron catalyzed decomposition of ethyleneCatalysis Today, 1997
- Catalytic Engineering of Carbon NanostructuresLangmuir, 1995
- A review of catalytically grown carbon nanofibersJournal of Materials Research, 1993
- Deactivation of Copper Nickel-Catalysts Due to Changes in Surface CompositionJournal of Catalysis, 1993
- Mechanism of carbon filament growth on metal catalystsJournal of Catalysis, 1989