Synthesis and X-ray crystal structure analysis of a novel µ4-oxo undeca-osmium carbonyl cluster [Os11(µ4-O)3(CO)30]
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 166-167
- https://doi.org/10.1039/c39930000166
Abstract
The first example of an osmium cluster containing µ4-oxo groups, [Os11(µ4-O)(CO)30]1, has been obtained from the vacuum pyrolysis of [Os3H(CO)10(µ-OH)], and has been shown by X-ray crystallography to contain a tri-edge bridged, bicapped trigonal prismatic metal core.Keywords
This publication has 13 references indexed in Scilit:
- (nBu4P)2[Os20(CO)40], a Thermolytically Generated High‐Nuclearity Cluster with a Tetrahedral Cubic‐Close‐Packed Metal CoreAngewandte Chemie International Edition in English, 1991
- Synthesis and X-ray crystal structure analysis of the largest binary osmium carbonyl cluster: [Os17(CO)36]2?Journal of the Chemical Society, Chemical Communications, 1990
- Synthesis and structure of a capped square-pyramidal five-metal oxo cluster, [Fe2Ru3(CO)14(.mu.4-O)]2-Journal of the American Chemical Society, 1989
- Synthesis of the cluster dianion [Os11C(CO)27]2–by pyrolysis and its reactions with electrophiles; X-ray structure analysis of the mixed-metal derivative [PMePh3][Os11C(CO)27{Cu(NCMe)}]·CH2Cl2and the hydrido derivative [PMePh3][Os11C(CO)27H]J. Chem. Soc., Dalton Trans., 1989
- Electron counting in square-pyramidal organo-transition-metal carbides: can a carbon atom be a vertex of a closo octahedral M5C clusterOrganometallics, 1986
- Metal-induced cleavage of carbon-sulfur bonds in thiolato ligands. Thermolysis of HOs3(CO)10(.mu.-SC6H5) under carbon monoxide pressure. The synthesis and crystal and molecular structures of Os4(CO)13(.mu.3-S) and Os5(CO)15(.mu.4-S)Organometallics, 1983
- The synthesis of the cluster dianion [Os10C(CO)24]2? by pyrolysis. X-Ray structure analysis of [N(PPh3)2]2[Os10C(CO)24] and [Os5C(CO)14H(NC5H4)]J. Chem. Soc., Dalton Trans., 1982
- Clusters and surfacesChemical Reviews, 1979
- The chemistry of polynuclear compounds. Part XXVI. Products of the pyrolysis of dodecacarbonyl-triangulo-triruthenium and -triosmiumJ. Chem. Soc., Dalton Trans., 1975
- Products from the pyrolysis of Ru3(CO)12 and Os3(CO)12Journal of Organometallic Chemistry, 1972