α-C-Glycopyranosides from Lewis acid catalysed condensations of acetylated glycals and enol silanes
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 1180-1181
- https://doi.org/10.1039/c39810001180
Abstract
Acetylated glycals undrgo Lewis acid-catalysed condensations with enol silanes in virtually quantitative yields to form C-glycopyranosides in which the termo-dynamically unfavourable α-‘anomers’ are formed predominantly.Keywords
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