THE INFRARED FREQUENCIES AND INTENSITIES OF THE HYDROXYL BAND OF ORTHO-ALKYL PHENOLS IN THE VAPOR PHASE
- 1 January 1962
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 40 (1) , 111-121
- https://doi.org/10.1139/v62-017
Abstract
The infrared frequencies and intensities of the fundamental stretching vibration of the hydroxyl group have been measured for a number of ortho-alkyl phenols in the vapor phase over a range of temperatures. Both quantities have been shown to depend on internal steric and environmental factors. The differences in enthalpy between the cis and trans isomers of several 2-tert-alkyl phenols have been measured, and it is concluded that the latter are not significantly stabilized relative to the former by solvation in non-polar solvents.Keywords
This publication has 2 references indexed in Scilit:
- Hydroxyl Spectra of o-t-ButylphenolsJournal of the American Chemical Society, 1960
- The Intensity of the Hydroxyl Band in Infra-Red SpectraAustralian Journal of Chemistry, 1959