NEW COMPLEXES OF PALLADIUM(II) CHLORIDE WITH CHELATING PHOSPHORUS, SULFUR CONTAINING LIGANDS

Abstract
New palladium(II) coordination compounds PdLCl2 and PdL2Cl2 with chelating ligands containing thiophosphoryl groups along with carbamoyl or thiocarbamoyl groups were synthesized. The structures of the complexes in solutions and in solid were studied by electronic and IR spectroscopy, conductometry, and FD mass spectrometry. Transformations of the complex PdL3 2Cl2 under a strong electric field were investigated.