Enantioselective Catalyses 110.1 New Chiral Phosphanes Derived from Substituted Quinolines
- 1 November 1997
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 1997 (11) , 1309-1314
- https://doi.org/10.1055/s-1997-1339
Abstract
Optically active, two-layer phosphanes were obtained by reaction of quinolineamines with metalated 1,2-bisphosphanylbenzene and chiral monodentate quinolinephosphanes were synthesized by reaction of optically active quinolineamines with lithium diphenylphosphide. The precursors were built up from quinoline derivatives containing bromomethyl groups and chiral secondary amines.Keywords
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