Resolving Electron Transfer Kinetics at the Nanocrystal/Solution Interface
- 29 March 2006
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 128 (15) , 4922-4923
- https://doi.org/10.1021/ja057474o
Abstract
The kinetics of electron transfer between individual gold nanocrystals and a solution redox species is quantified. The observed rate is dependent on the extent of electronic coupling between nanocrystals in the monolayer indicating the effect of Coulomb blockade on electrochemical kinetics.Keywords
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