Synthesis and crystal and solution structures of the 1 : 1 TMEDA complex of lithium thiocyanate, (LiSCN·TMEDA)n[TMEDA = Me2N(CH2)2NMe2]: a polymeric solid with Li+ions linked by bifunctional linear SCN–ligands
- 1 January 1988
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 145-147
- https://doi.org/10.1039/c39880000145
Abstract
The anhydrous complex (LiSCN·TMEDA)n(1)[TMEDA = Me2N(CH2)2NMe2] has been synthesised by a novel in situ route from solid NH4SCN and BunLi in TMEDA/hexane, and shown to have a polymeric chain crystal structure with Li–N[graphic omitted]CS ⋯ Li repeat units; in hydrocarbon solvents, however, (1) adopts a dimeric, purely N–Li bridged structure.Keywords
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