Addition compounds of 1,3,5-trithian with mercury(II) and silver(I) salts
- 1 January 1966
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 233-235
- https://doi.org/10.1039/j19660000233
Abstract
The preparation from ethanolic solution and analysis of the 1 : 1 addition compounds C3H6S3,HgX2 where X = Cl, Br, and I are described. The trithian can be recovered by extraction into benzene in the presence of hydrochloric acid. The preparation from aqueous solution and analysis of the 1 : 1 addition compounds C3H6S2,AgNO3, C3H6S3,AgNO3,H2O, and C3H6S3,AgBF4,H2O are also described. Conductivity measurements show that the (C3H6S3Ag)+ ion exists in aqueous solution. The 1 : 1 addition compounds C3H6S3,AgX, prepared by the reaction of the nitrate with the appropriate alkali halide, have been analysed. Their photosensitivity differs from that of the simple silver halides. The unit-cell dimensions, cell contents, and X-ray diffraction powder data are reported.Keywords
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