The reaction of CH3O2 radicals with NO2
- 1 January 1980
- journal article
- research article
- Published by Wiley in International Journal of Chemical Kinetics
- Vol. 12 (1) , 1-16
- https://doi.org/10.1002/kin.550120102
Abstract
The rate constant for the reaction CH3O2 + NO2 → (products) has been measured directly by flash photolysis and kinetic spectroscopy. At room temperature and at total pressures between 53 and 580 Torr, k3 = (9.2 ± 0.4) × 108 liter/mole sec so that the rate of formation of the probable primary product peroxymethyl nitrate (CH3O2NO2) may be significant in urban atmospheres.Keywords
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