The Stereochemistry of the Reduction of Carbon–Carbon Double Bond with the Cultured Cells of Nicotiana tabacum
- 1 September 1986
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 59 (9) , 2865-2867
- https://doi.org/10.1246/bcsj.59.2865
Abstract
The stereochemistry in the reduction of the C–C double bond adjacent to the carbonyl group with the cultured cells of Nicotiana tabacum was investigated by feeding (4R)-[6-2H]-(−)-carvone to the cultured cells. It was found that the hydrogen attack to the C–C double bond takes place stereospecifically from the si-face at C-1 and the re-face at C-6, being trans-addition.Keywords
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