A Three-Dimensional Warp-and-Woof Structure Interwoven by a Couple of Two-Dimensional Network Layers in the Crystal Structure of [trans-Cd(NH3)2{Ag(CN)2}2]n
- 1 April 1995
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 24 (4) , 271-272
- https://doi.org/10.1246/cl.1995.271
Abstract
Two sets of the two-dimensional [Cd-(NC-Ag-CN-Cd1⁄4)4]n network layers arrayed vertically to each other interpenetrate through every mesh without any direct chemical bonds to build up the three-dimensionally interwoven supramolecular structure of the title complex.Keywords
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- Design and construction of a new class of scaffolding-like materials comprising infinite polymeric frameworks of 3D-linked molecular rods. A reappraisal of the zinc cyanide and cadmium cyanide structures and the synthesis and structure of the diamond-related frameworks [N(CH3)4][CuIZnII(CN)4] and CuI[4,4',4'',4'''-tetracyanotetraphenylmethane]BF4.xC6H5NO2Journal of the American Chemical Society, 1990