Utility of tris(dimethylamino)sulphonium difluorotrimethylsilicate (TASF) for the rapid synthesis of deoxyfluoro sugars
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 663-664
- https://doi.org/10.1039/c39850000663
Abstract
The fluoride ion displacement of carbohydrate trifluoromethanesulphonates using tris(dimethylamino)sulphonium difluorotrimethylsilicate (TASF) provides a convenient route to deoxyfluoro sugars; the rapidity of the reaction makes it of interest for the potential synthesis of fluorinated-carbohydrate radiopharmaceuticals for use in medical imaging.Keywords
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