Formation of abnormal products in the aluminium chloride-catalysed ene additions of chloral and bromal to mono- and 1,2-di-alkyl ethylenes
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 655-656
- https://doi.org/10.1039/c39780000655
Abstract
The title reactions afford products of apparent Friedel–Crafts acylation of the olefins by the acyl halides X2CHCOX (X = Cl or Br) as well as the expected ene adducts in many cases; the two types of products appear to be formed from a common dipolar intermediate.Keywords
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