Abstract
The high-density limit of the jellium model is used to study the kinetic energy T(z) of the electron gas as bulk jellium is separated into two half-planes at distance z. It is shown that, for qz1, where q1 is the Thomas-Fermi screening length, the Taylor expansion of T(z) around z=0 contains, in particular, a quadratic term with a coefficient proportional to rs112, where rs is the mean interelectronic separation. Using the virial theorem, this same rs dependence is shown to appear in the quadratic term in the expansion of the total energy E(z). It is thereby argued that in the limit rs0 the constant in the force F(z)=Az for small z in real metals, calculated from phonondispersion relations, must tend to a limit proportional to rs112. Possible implications of this result for prediction of the surface energy of simple metals are briefly considered.

This publication has 6 references indexed in Scilit: