Mass Spectra of Some Deuteroethanes.
- 1 March 1961
- journal article
- Published by National Institute of Standards and Technology (NIST) in Journal of Research of the National Bureau of Standards Section A: Physics and Chemistry
- Vol. 65 (2) , 93-95
- https://doi.org/10.6028/jres.065A.010
Abstract
Mass spectra of seven of the nine possible deuteroethanes have been measured. When the patterns are computed on a scale to make the sums of ions equal, it is found that the abundances of molecule ions differ nearly twofold in the different molecules, and there are large differences in the patterns of the two C2H4D2 molecules. The peaks in the C1 range are compared with the patterns predicted for simple breaking of the C-C bond and dissociation of the methyl radicals. The "weighting factors" for removing H and D, HD, and 2D, etc., from C2HD5 are computed and also the weighting factors for H+ and D+ for all the deuteroethanes are given.Keywords
This publication has 1 reference indexed in Scilit:
- Absolute Rate Theory for Isolated Systems and the Mass Spectra of Polyatomic MoleculesProceedings of the National Academy of Sciences, 1952