Comment on relativistic transition-probability calculations for the Be isoelectronic sequence
- 1 March 1977
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review A
- Vol. 15 (3) , 1326-1329
- https://doi.org/10.1103/physreva.15.1326
Abstract
Recent calculations of oscillator strengths by Armstrong, Fielder, and Lin employing relativistic multiconfiguration Hartree-Fock (MCHF) methods give a disparity between length- and velocity-gauge results. It is shown here that the disparity is due in part to the neglect of certain "exchange overlap" terms in the evaluations of transition-matrix elements in MCHF calculations. Including such exchange overlap terms brings velocity-gauge values into substantial agreement with length-gauge results for high- members of the Be isoelectronic sequence. The disparity for lower members of the sequence is increased and the resulting difference between length- and velocity-gauge values reflects the changing reliability of the MCHF calculation as increases along the sequence.
Keywords
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