Nuclear magnetic resonance studies of cyanide ion–2,4,6-trinitroanisole σ-complexes
- 1 August 1969
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 47 (15) , 2895-2897
- https://doi.org/10.1139/v69-482
Abstract
Nuclear magnetic resonance studies at −30 °C reveal that the cyanide ion reacts with 2,4,6-trini-troanisole to form σ-complexes by attachment of the cyanide ion at both the C-1 and C-3 positions on the ring. In contrast to the methoxide ion adducts of 2,4,6-trinitroanisole, the cyanide ion adduct resulting from attack of the cyanide at the C-3 position is the more stable species.Keywords
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