DABCO-Catalysed Dimerisation of Some ?,?-Unsaturated Esters
- 1 July 1990
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 20 (13) , 1915-1921
- https://doi.org/10.1080/00397919008053121
Abstract
Aerylate esters readily undergo the Baylis-Hillman reaction with aldehydes in the presence of DABCO. In the absence of aldehydes it has now been established that esters with good leaving groups undergo self condensation (Michael addition) to afford dimers in almost quantitative yield.Keywords
This publication has 9 references indexed in Scilit:
- Stereoselective generation and facile dimerization of (E)-2-methylene-3-alkenoic acid estersThe Journal of Organic Chemistry, 1988
- Synthetic potential of the tertiary-amine-catalysed reaction of activated vinyl carbanions with aldehydesTetrahedron, 1988
- DABCO catalyzed dimerization of α,β-unsaturated ketones and nitrilesTetrahedron Letters, 1987
- Hydroxyalkylation de la methylvinylcetone et de l'acrylonitrile en presence de diaza-1,4 bicyclo [2.2.2] octaneTetrahedron Letters, 1986
- Diastereoface-discriminative metal coordination in asymmetric synthesis: D-pantolactone as practical chiral auxiliary for Lewis acid catalyzed Diels-Alder reactionsTetrahedron Letters, 1985
- A selective dimerization reaction of methyl crotonate by aluminum alkyl-sparteine complexTetrahedron Letters, 1972
- Synthetic reactions by complex catalysts. XV. Copper(I)-alkyl isocyanide catalyzed dimerization of .alpha.,.beta.-unsaturated carbonyl and nitrile compoundsThe Journal of Organic Chemistry, 1970
- Olefin-to-Olefin Addition ReactionsJournal of the American Chemical Society, 1965
- Electrolytic Reductive Coupling. VIII.1 Utilization and a New Preparation of α-MethyleneglutaronitrileThe Journal of Organic Chemistry, 1965