Potentiometric techniques applied to the modelling of actinide migration in natural water systems†
- 1 July 1985
- journal article
- research article
- Published by Taylor & Francis in Toxicological & Environmental Chemistry
- Vol. 10 (3) , 257-264
- https://doi.org/10.1080/02772248509357106
Abstract
The utility of potentiometric techniques applied to environmental problems is discussed. The applicability of this technique to the estimation of thermodynamic quantities important for the modelling of uranium migration in natural waters is demonstrated. An experimental methodology for the determination of the UO2(s) solubility product and the UO2+/U4+ redox potentials is proposed.Keywords
This publication has 6 references indexed in Scilit:
- Studies on metal carbonate equilibria. Part 10. A solubility study of the complex formation in the uranium(VI)–water–carbon dioxide (g) system at 25 °CJ. Chem. Soc., Dalton Trans., 1984
- The solubility of uranium(IV) hydrous oxide in sodium hydroxide solutions under reducing conditionsPolyhedron, 1983
- Solubility of uranium (IV) oxide in alkaline aqueous solutions to 300 CJournal of Solution Chemistry, 1981
- Oxidation-reduction potential of UO22+U4+ system in perchloric acidJournal of Inorganic and Nuclear Chemistry, 1961
- Chemistry of Aqueous Uranium(V) Solutions. II. Reaction of Uranium Pentachloride with Water. Thermodynamic Stability of UO2+. Potential of U(IV)/(V), U(IV)/(VI) and U(V)/(VI) CouplesJournal of the American Chemical Society, 1949
- Das elektromotorische Verhalten von Uranyl‐UranogemengenBerichte der Bunsengesellschaft für physikalische Chemie, 1908