Replacing Phosphorus with Sulfur for the Efficient Hydrogenation of Esters
- 28 January 2013
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 52 (9) , 2538-2542
- https://doi.org/10.1002/anie.201209218
Abstract
Catalyst tune-up: A readily available, air-stable amino–sulfide catalyst, [RuCl2(PPh3){HN(C2H4SEt)2}], has been developed. This complex displays outstanding efficiency for the hydrogenation of a broad range of substrates with CX bonds (esters, ketones, imines), as well as for the acceptorless dehydrogenative coupling of ethanol to ethyl acetate (see scheme).Keywords
This publication has 44 references indexed in Scilit:
- From Esters to Alcohols and Back with Ruthenium and Osmium CatalystsAngewandte Chemie, 2012
- Efficient hydrogenation of organic carbonates, carbamates and formates indicates alternative routes to methanol based on CO2 and CONature Chemistry, 2011
- Metal–Ligand Cooperation by Aromatization–Dearomatization: A New Paradigm in Bond Activation and “Green” CatalysisAccounts of Chemical Research, 2011
- New CNN-Type Ruthenium Pincer NHC Complexes. Mild, Efficient Catalytic Hydrogenation of EstersOrganometallics, 2011
- An Efficient Synthesis of Chiral Alcohols via Catalytic Hydrogenation of EstersTopics in Catalysis, 2010
- A Homogeneous Catalyst for Reduction of Optically Active Esters to the Corresponding Chiral Alcohols without Loss of Optical PuritiesAdvanced Synthesis & Catalysis, 2010
- Dihydrogen Reduction of Carboxylic Esters to Alcohols under the Catalysis of Homogeneous Ruthenium Complexes: High Efficiency and Unprecedented ChemoselectivityAngewandte Chemie International Edition in English, 2007
- Dihydrogen Reduction of Carboxylic Esters to Alcohols under the Catalysis of Homogeneous Ruthenium Complexes: High Efficiency and Unprecedented ChemoselectivityAngewandte Chemie, 2007
- Efficient Homogeneous Catalytic Hydrogenation of Esters to AlcoholsAngewandte Chemie International Edition in English, 2006
- Efficient Homogeneous Catalytic Hydrogenation of Esters to AlcoholsAngewandte Chemie, 2006