Mid-infrared reflectivity and ellipsometry measurements on single-crystal YBa2Cu3O7 and Bi2Sr2CuO6+y

Abstract
We have measured the room-temperature reflectivity of ‘‘90-K’’ single crystals YBa2 Cu3 O7 in the frequency range 600–9000 cm1. The reflectivity R in these highly conducting samples (ρab=150 μΩ cm at 290 K) is found to be higher than in previous reports. We fit R to a simple Drude-Lorentz model and compare the fit parameters with the dc transport values. (The effective-mass ratio of the carriers is found to be 2.0, and the scattering rate ħ/τ is 3.1kBT at room temperature.) Ellipsometry measurements have also been performed using transverse-electric and transverse-magnetic polarizations. The dielectric dispersion derived from ellipsometry shows some important deviations from the Drude-Lorentz model. Reflectivity data from nonsuperconducting crystals of Bi2 Sr2 CuO6+y are also reported.