Construction of 8-Membered Ring Skeleton of Vinigrol via SmI2-Promoted Barbier Coupling
- 1 February 1997
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1997 (2) , 219-220
- https://doi.org/10.1055/s-1997-748
Abstract
The 8-membered ring framework of vinigrol, a unique tricyclic diterpene isolated as a novel antihypertensive compound from a culture of Virgaria nigra, was efficiently synthesized employing an SmI2-induced intramolecular Barbier coupling.Keywords
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