A novel left-handed double helicate constructed from l-tartrate bridged molybdenum(vi) and gadolinium(iii) atomsElectronic supplementary information (ESI) available: crystallographic data, TGA, powder X-ray patterns, ORTEP structure and molar susceptibility plot for compound 1. See http://www.rsc.org/suppdata/cc/b3/b301542d/
- 2 May 2003
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 11,p. 1284-1285
- https://doi.org/10.1039/b301542d
Abstract
The one-dimensional double helicate, [NH4][Mo2O4Gd(H2O)6(L-C4H2O6)2]·4H2O (1), which was synthesized by the reaction of GdCl3, L-tartaric acid and ammonium molybdate in acidified water solution, is built up by two heft-handed single-helical chains, linked up further by eight-coordinated GdIII pieces in an enantiopure left-handed double helical configuration, of which each helix is formed by L-tartrate bridged six-coordinated MoVI atoms.Keywords
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