Amino-derivatives of metals and metalloids. Part IV. Aminosilylation and aminophosphination of some unsaturated substrates

1 January 1966

journal article
research article
Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A

p. 82-85
https://doi.org/10.1039/j19660000082

Abstract

The aminometallation of carbon dioxide and disulphide, and phenyl iso- and isothio-cyanate are described, using Me₂Si(NEt₂)₂, Me₂Si(NHEt)₂, PhP(NMe₂)₂, and PhP(NMe₂)Cl. The results are correlated with data on other systems. Structures are suggested for the new carbamato-, dithiocarbamato-, ureido-, and thioureido-silanes and -phosphines, on the basis of alcoholyses, infrared spectra, and analogy with previously studied systems.

Keywords

STRUCTURES
ME2SI
NME2
PHP
STUDIED SYSTEMS
CARBON DIOXIDE
UNSATURATED SUBSTRATES
PHENYL ISO
THIOUREIDO SILANES
INFRARED SPECTRA

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