Organometallic additions to protected quinone bis-epoxides and quinone monoacetals: synthesis of the aranorosin nucleus
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 1589-1591
- https://doi.org/10.1039/c39920001589
Abstract
The addition reactions of organometallic reagents to monoprotected quinone bis-epoxides 7 and quinone monoacetals 5 provide a route to the highly oxygenated cyclohexanols 2 and 3; the application of this methodology to the preparation of the aranorosin analogue 4 is described.Keywords
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