The decarbonylation of aldehydes by tris(triphenylphosphine)chlororhodium(I)
- 1 January 1968
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 348-351
- https://doi.org/10.1039/j19680000348
Abstract
The observed rate for the decarbonylation of n-valeraldehyde by tris(triphenylphosphine)chlororhodium(I), RhCl(PPh3)3, in dichloromethane solution at 20° is given by the equation: Rate =k1[RhCl(PPh3)3]+k2[RhCl(PPh3)3][C4H9CHO], where k1= 5·68 × 10–5 sec.–1 and k2= 1·81 × 10–4 l. mole–1 sec.–1.Keywords
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