Nanoassembly of a Fractal Polymer: A Molecular "Sierpinski Hexagonal Gasket"
Top Cited Papers
- 23 June 2006
- journal article
- other
- Published by American Association for the Advancement of Science (AAAS) in Science
- Vol. 312 (5781) , 1782-1785
- https://doi.org/10.1126/science.1125894
Abstract
Mathematics and art converge in the fractal forms that also abound in nature. We used molecular self-assembly to create a synthetic, nanometer-scale, Sierpinski hexagonal gasket. This nondendritic, perfectly self-similar fractal macromolecule is composed of bis-terpyridine building blocks that are bound together by coordination to 36 Ru and 6 Fe ions to form a nearly planar array of increasingly larger hexagons around a hollow center.Keywords
This publication has 16 references indexed in Scilit:
- Mass spectrometry analysis of organometallic assemblies: Bis-terpyridine-Ru(II) connectivityInternational Journal of Mass Spectrometry, 2006
- Nanofabrication: Reversible Self‐Assembly of an Imbedded Hexameric Metallomacrocycle within a Macromolecular SuperstructureAngewandte Chemie International Edition in English, 2005
- Probing the Conformation of Physisorbed Molecules at the Atomic Scale Using STM ManipulationNano Letters, 2004
- Towards Ordered Architectures: Self‐Assembly and Stepwise Procedures to the Hexameric Metallomacrocycles [Arylbis(terpyridinyl)6FeII6−n‐RuIIn] (n=0,2,3,5)Chemistry – A European Journal, 2004
- Synthesis, X-ray Structure, and Self-Assembly of Functionalized Bis(2,2‘:6‘,2‘ ‘-terpyridinyl)arenesOrganic Letters, 2004
- High Lateral Resolution Imaging with Sharpened Tip of Multi-Walled Carbon Nanotube Scanning ProbeThe Journal of Physical Chemistry B, 2004
- Molecular Graphics: From Science to ArtCrystal Growth & Design, 2002
- Ruthenium(II) and Osmium(II) Bis(terpyridine) Complexes in Covalently-Linked Multicomponent Systems: Synthesis, Electrochemical Behavior, Absorption Spectra, and Photochemical and Photophysical PropertiesChemical Reviews, 1994
- Electronic absorption spectra of the iron(II) complexes of 2,2'-bipyridine, 2,2'-bipyrimidine, 1,10-phenanthroline, and 2,2':6',2''-terpyridine and their reduction productsInorganic Chemistry, 1992
- Micelles. Part 1. Cascade molecules: a new approach to micelles. A [27]-arborolThe Journal of Organic Chemistry, 1985