Crown thioether complexes of p-block elements: crystal and molecular structures of SbCl3·9s3 (9s3 = 1,4,7-trithiacyclononane) and 2SbCl3·18S6 (18S6 = 1,4,7,10,13,16-hexathiacyclooctadecane)
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 271-272
- https://doi.org/10.1039/c39910000271
Abstract
The first crown thioether complexes of SbIII and BiIII, as representative p-block elements, have been isolated, viz SbCl3·9S31, BiCl3·9S3·0.5 MeCN, SbCl3·15S5, 2SbCl3·18S6 2 and BiCl3·18S6; X-ray crystal structure determinations of 1 and 2 establish full participation of ligand S-donor sites in metal ⋯ sulphur bonding in each case.Keywords
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