Electric Polarization of Carboxylic Acids in Dilute Solutions of Nonpolar Solvents I. The Relation of Electric Polarization to the Association of Carboxylic Acids in Hydrocarbon Solvents
- 1 May 1941
- journal article
- conference paper
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 9 (5) , 408-414
- https://doi.org/10.1063/1.1750924
Abstract
The association and polar character of various carboxylic acids have been studied in the solvents benzene and heptane by means of measurements of the electric polarization in very dilute solutions. The data have been analyzed by assuming an equilibrium between dimers and monomers of the acid molecules. A rather large anomalous contribution to the polarization of the dimer has been found. Possible origins of this polarization have been briefly considered.Keywords
This publication has 7 references indexed in Scilit:
- POLARIZATION MEASUREMENTS ON CARBOXYLIC ACIDS IN DILUTE SOLUTION IN NON‐POLAR SOLVENTSAnnals of the New York Academy of Sciences, 1940
- The Electric Moments of Some Substituted Benzoic AcidsJournal of the American Chemical Society, 1940
- An Apparatus for the Determination of the Electric Moment of MoleculesReview of Scientific Instruments, 1940
- Dipole induction and the solvent effect in dipole moment measurementsProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1935
- Dipole Moment and Group Rotation. I. The Moments of the Chloro- and Nitrobenzyl Chlorides and the Effect of Group Separation1Journal of the American Chemical Society, 1933
- Travaux du bureau international d'étalons physico-chimiquesJournal de Chimie Physique et de Physico-Chimie Biologique, 1930
- Travaux du bureau international d’étalons physico-chimiquesJournal de Chimie Physique et de Physico-Chimie Biologique, 1926