Assigned cluster11B and1H NMR properties of [3‐(η6‐C6Me6)‐closo‐3,1,2‐RuC2B9H11]
- 1 October 1989
- journal article
- research article
- Published by Wiley in Magnetic Resonance in Chemistry
- Vol. 27 (10) , 947-949
- https://doi.org/10.1002/mrc.1260271008
Abstract
The cluster11B chemical shifts in members of the important class ofcloso‐3,1,2‐metalladicarbaboranes were previously unassigned, and their cluster1H chemical shifts previously unmeasured. The use of [11B11B]‐COSY and1H‐{11B} NMR spectroscopy to measure and assign the cluster11B and1H chemical shifts of (previously unreported) [3‐(η6‐C6Me6)‐closo‐3,1,2‐RuC2B9H11] as a model compound is reported. The11B shielding patterns of this species and the nonmetalla simple carbaborane analogue [1,2‐C2B10H12] are compared and briefly discussed.Keywords
This publication has 12 references indexed in Scilit:
- Synthesis and molecular structure of closo-3-(.eta.6-CH3C6H5)-3,1,2-FeC2B9H11 and closo-3-[.eta.6-1,4-(CH3)2C6H4]-3,1,2-FeC2B9H11Inorganic Chemistry, 1987
- Organo-ruthenaborane and -osmaborane cluster compounds: preparation and NMR studies of [6-(η6-C6Me6)-nido-6-MB9H13] (M = Ru, Os) and the rearranged cluster [5-(η6-C6Me6)-nido-5-RuB9H11-7-(PMe2Ph)]Journal of Organometallic Chemistry, 1987
- BoronPublished by Springer Nature ,1987
- Substitution of arachno-4,6-c2b7h13 carboranePolyhedron, 1986
- Synthesis of (.pi.-arene)metallacarbaboranes containing ruthenium or osmium and a (.pi.-cyclohexadienyl)cobaltacarbaborane. Crystal structure of 2,5,6-(.eta.-C6H6)RuC2B7H11Inorganic Chemistry, 1985
- Potassium dodecahydro‐7, 8‐dicarba‐ nido ‐undecaborate(1‐), k[7, 8‐c 2 b 9 h 12 ], intermediates, stock solution, and anhydrous saltPublished by Wiley ,1984
- Two-dimensional boron-11-boron-11 nuclear magnetic resonance spectroscopy as a probe of polyhedral structure: application to boron hydrides, carboranes, metallaboranes, and metallacarboranesJournal of the American Chemical Society, 1984
- Synthesis of π-(arene)metallocarboranes containing iron and ruthenium. Crystal structure of 3,1,2-(η6-1,3,5-(CH3)3C6H3)FeC2B9H11Polyhedron, 1982
- 16. (η 6 ‐Hexamethylbenzene)Ruthenium ComplexesPublished by Wiley ,1982
- A13C and31P magnetic double resonance study of organo-phosphorus compoundsProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1968