Rate Coefficients of Elementary Steps in the Inhibited Oxidation of Ethylbenzene, II. Interaction between Hydroperoxide and Alcohol Molecules
- 1 January 1984
- journal article
- research article
- Published by Wiley in Berichte der Bunsengesellschaft für physikalische Chemie
- Vol. 88 (1) , 63-65
- https://doi.org/10.1002/bbpc.19840880115
Abstract
The decomposition of 1‐phenylethyl‐hydroperoxide assisted by 1‐phenyl‐ethanol has been investigated in the presence of 2,6‐di‐tert‐butyl‐4‐methyl‐phenol (ionol). Ethylbenzene was used as solvent, the temperature range was 115–130°C. The inhibition period was measured as a function of alcohol concentration (and inhibitor concentration as well). The activation parameters of hydroperoxide decomposition assisted by alcohol have been determined:kHROOH + HROH = 1.13 · 107 exp(94.9 kJ mol‐1/RT) s‐1Keywords
This publication has 3 references indexed in Scilit:
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