Preparation and crystal structure of (OC)5OsOs(CO)3(GeCl3)(Cl): a compound with an unsupported, donor–acceptor metal–metal bond
- 1 January 1983
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 854-855
- https://doi.org/10.1039/c39830000854
Abstract
The crystal structure of (OC)5OsOs(CO)3(GeCl3)(Cl)[prepared from Os(CO)5 and GeCl4] reveals that the Os(CO)5 unit acts as a donor ligand towards the second osmium atom via an unsupported, donor–acceptor Os–Os bond.Keywords
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