Kinetics of oxidation of organic compounds by silver(II) in aqueous perchloric acid solution. Part 3. Aliphatic aldehydes
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 1,p. 77-80
- https://doi.org/10.1039/p29780000077
Abstract
The stoicheiometries and kinetics of the silver(II) oxidation of formaldehyde, acetaldehyde, propionaldehyde, n-butyraldehyde, isobutyraldehyde, and pivaldehyde have been investigated at 8.0, 14.0, and 22.0 °C in aqueous perchloric acid media (1.00 [HClO4] 4.00M; µ 4.0M). The kinetics were monitored by a stopped flow technique. The reactions occur with the stoicheiometry H2O + 2AgII+ RCHO → 2AgI+ 2H++ RCOOH. The rate-determining step is first order in each reactant, and involves both Ag2+ and AgOH+ species. No direct evidence for complex formation between the reactants was obtained. The results are discussed with reference to enolization and hydration equilibria of the substrates. gem-Diol forms of the aldehydes are suggested as the active species.Keywords
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