A hydrogenase model system based on the sequence of cytochrome c: photochemical hydrogen evolution in aqueous media
- 26 April 2011
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- Vol. 47 (29) , 8229-8231
- https://doi.org/10.1039/c1cc11157d
Abstract
The diiron carbonyl cluster is held by a native CXXC motif, which includes Cys14 and Cys17, in the cytochrome c sequence. It is found that the diiron carbonyl complex works well as a catalyst for H2 evolution. It has a TON of ∼80 over 2 h at pH 4.7 in the presence of a Ru-photosensitizer and ascorbate as a sacrificial reagent in aqueous media.This publication has 46 references indexed in Scilit:
- Hydride-Containing Models for the Active Site of the Nickel−Iron HydrogenasesJournal of the American Chemical Society, 2010
- Modification of Porous Protein Crystals in Development of Biohybrid MaterialsBioconjugate Chemistry, 2010
- Selective Protein‐Surface Sensing Using Ruthenium(II) Tris(bipyridine) ComplexesChemistry – A European Journal, 2009
- Photoinduced Hydrogen-Evolution System with an Antibody–Porphyrin Complex as a PhotosensitizerBulletin of the Chemical Society of Japan, 2009
- Small molecule mimics of hydrogenases: hydrides and redoxChemical Society Reviews, 2008
- Photocatalytic hydrogen generation using a protein-coated photosensitizer with anionic patches and a monocationic electron mediatorChemical Communications, 2008
- Thiolate-bridged dinuclear iron(tris-carbonyl)–nickel complexes relevant to the active site of [NiFe] hydrogenaseProceedings of the National Academy of Sciences, 2008
- Synthetic Hydrogenases: Incorporation of an Iron Carbonyl Thiolate into a Designed PeptideJournal of the American Chemical Society, 2007
- Hopping and Annihilation of3MLCT in the Crystalline Solid of [Ru(bpy)3]X2(X = Cl-, ClO4-and PF6-)The Journal of Physical Chemistry A, 2000
- High-driving-force electron transfer in metalloproteins: intramolecular oxidation of ferrocytochrome c by Ru(2,2'-bpy)2(im)(his-33)3+Journal of the American Chemical Society, 1991