A new synthetic approach to 3-amino-1,2-diols from allylic alcohols via trichloroacetimidates
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 1489-1490
- https://doi.org/10.1039/c39830001489
Abstract
A new regioselective iodoamination reaction of allylic trichloroacetamides is described; the iodoaminoalcohols are obtained as the salts (5)via the corresponding 4,5-dihydro-1,3-oxazoles (4), and (4a) is converted by hydrolysis into the salt of the 3-amino-1,2-diol (9a).Keywords
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