Olefin metatheses in metal coordination spheres: novel trans-spanning bidentate and facially-spanning tridentate macrocyclic phosphine complexes
- 6 November 2000
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 22,p. 2261-2262
- https://doi.org/10.1039/b007405p
Abstract
The title reaction is applied to square-planar rhodium and platinum complexes with trans PPh2(CH2)6CHCH2 ligands, and square-planar platinum or octahedral tungsten complexes with trans or facial PPh[(CH2)6CHCH2]2 ligands. Ring-closing (poly)macrocyclizations occur.Keywords
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