Novel Convenient Method for the Synthesis of N,N-Bis(trimethylsilyloxy)enamines
- 1 February 1998
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 1998 (02) , 181-185
- https://doi.org/10.1055/s-1998-2019
Abstract
Both primary and secondary aliphatic nitro compounds 1 were found to react with two equivalents of bromotrimethylsilane in the presence of triethylamine followed by aqueous workup to give appropriate N,N-bis(trimethylsilyloxy)enamines 3 in good isolated yields. Products 3, starting from some secondary and/or sterically hindered compounds 1, are synthesized from the corresponding silyl nitronates 2.Keywords
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