Noncritical behavior of density fluctuations in supercooled water
- 27 September 1993
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 71 (13) , 2050-2053
- https://doi.org/10.1103/physrevlett.71.2050
Abstract
We have measured the absolute structure factor of liquid water over the wave-number range 0.05<k<0.30 A and temperature range -34<T<25 °C with small-angle x-ray scattering. The correlation lengths of density fluctuations are small and change very little with temperature, suggesting that supercooled water may not be approaching a proposed spinodal point. The increasing density fluctuations with supercooling in water appear to be due to an increasing fraction of water molecules participating in clusters, not an increasing range of correlations.
Keywords
This publication has 22 references indexed in Scilit:
- Phase behaviour of metastable waterNature, 1992
- Supercooled WaterAnnual Review of Physical Chemistry, 1983
- Densities and partial molar volumes of supercooled aqueous solutionsThe Journal of Chemical Physics, 1983
- The viscosity of supercooled aqueous solutions of ethanol and hydrazineThe Journal of Chemical Physics, 1982
- Interpretation of the unusual behavior of H2O and D2O at low temperatures: Tests of a percolation modelThe Journal of Chemical Physics, 1980
- Water RevisitedScience, 1980
- Isothermal compressibility of supercooled water and evidence for a thermodynamic singularity at −45°CThe Journal of Chemical Physics, 1976
- Clustering in supercooled waterThe Journal of Chemical Physics, 1973
- Observed Diffraction Pattern and Proposed Models of Liquid WaterScience, 1969
- Effect of Pressure on Sound Propagation in WaterJournal of Applied Physics, 1955