Three Novel Gibberellins Produced byGibberella fujikuroi

Abstract
Three novel gibberellins, GA54 (ent-1.alpha., 3.alpha., 10-trihydroxy-20-norgibberell-16-ene-7, 19-dioic acid 19, 10-lactone), GA55 (ent-1.alpha., 3.alpha., 10, 13-tetrahydroxy-20-norgibberell-16-ene-7, 19-dioic acid 19, 10-lactone) and GA56 (ent-2.beta., 3.alpha., 10, 13-tetrahydroxy-20-norgibberell-16-ene-7, 19-dioic acid 19, 10-lactone) occurred in the culture broth of G. fujikuroi. Their structures were determined mainly by mass spectrometrical comparison of the derivatives with those of authentic compounds prepared from known gibberellins.

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