Determination of Methyl- and Ethylmercury in Natural Waters at Sub-nanogram per Liter Using SCF-Adsorbent Preconcentration Procedure

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Abstract
An analytical procedure for determining methyl- and ethylmercury (MeHg/EtHg) in natural waters is described. MeHg/EtHg was preconcentrated from water on a sulfhydryl cotton fiber (SCF) adsorbent and eluted with a small volume of a mixture of 1 M hydrochloric acid and 2 M sodium chloride. The eluate was extracted with benzene. The measurements of MeHg/EtHg in benzene extract were determined by gas chromatography with electron capture detector. The detection limit for MeHg/EtHg was about 0.04ng L−1 using a 20 L water sample. The precision was about 20%. The application of the proposed method to one snow and four freshwater samples varying in humus content is described. The MeHg concentrations found in different freshwater samples were ranged from 0.09 to 0.22 ng L−1 and the recoveries of spiked MeHg were ranged from 42 to 68% which were strongly correlated to the content of humic substances. The MeHg concentration found in snow was 0.28 ng L−1 and the recovery was 79%. The analytical results of MeHg concentration in freshwater samples are discussed in relation to the pH used in the preconcentration, the humus content, the fraction of methylmercury in organic bound mercury and mercury in fish.