Some complexes of Fe(II) with thiourea ligands
Open Access
- 15 May 1967
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 45 (10) , 1135-1142
- https://doi.org/10.1139/v67-191
Abstract
Fe(thiourea)2(SCN)2, Fe(thiourea)4Cl2, and FeL2Cl2 (where L = methylthiourea, 1,3-dimethylthiourea, and 1,3-diethylthiourea) have been prepared and characterized. Magnetic moments and ligand field spectra indicate that all are octahedral. Infrared spectra show that the thiourea and methylthiourea ligands coordinate through the sulfur atom; the other two ligands are probably sulfur bonded also. The thiocyanate ion is coordinated through the nitrogen.Keywords
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