A New Efficient Method for Stereoselective Synthesis of 2-Deoxy-C-ribofuranosides
- 1 August 1996
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 25 (8) , 629-630
- https://doi.org/10.1246/cl.1996.629
Abstract
Stereoselective C-glycosylation of 2-deoxyribose derivatives having 3-O-thiocarbamoyl directing group with carbon nucleophiles was successfully carried out by using SiCl(OTf)3 as an activator. Several 2-deoxy-β-C-ribofuranosides which can be easily converted to 2′-deoxy-C-nucleosides were obtained in good yields with high stereoselectivities.Keywords
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