Polymerization in the crystalline state. III. Methacrylic acid and butadiene‐1‐carboxylic acid
- 1 March 1962
- journal article
- research article
- Published by Wiley in Journal of Polymer Science
- Vol. 57 (165) , 687-692
- https://doi.org/10.1002/pol.1962.1205716554
Abstract
Methacrylic acid polymerized in the solid state leads to a much less syndiotactic polymer than when polymerized in the liquid state. This is taken as additional evidence for the importance of the geometry of the monomer crystal lattice in solid state polymerization. Butadiene‐1‐carboxylic acid polymerizes spontaneously in the solid state to a cross‐linked product, while the sodium, potassium, and barium salts of this acid are stable and polymerize very little, even on gamma‐ray irradiation.Keywords
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